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}a#fan_trigger { color: #5C88C0; }div.MEMOBODY, div.BLOGPARTS, div.FANBODY { width: 170px; overflow: hidden;}div.BLOGPARTS > div { margin: 0 auto;}.thumnail_next_bbs { border: solid 1px #cdcdcd !important; margin: 0 !important; padding: 4px; float: left; display: block; width: 88px; height: 88px;}.bbs_preview { width: 500px; clear: both;}/style> /head>body idtop-page> div idgpt_pc_blog_overlay> script defer typetext/javascript src//image.excite.co.jp/jp/ox/gpt/display/pc/blog/pc_blog_overlay.js>/script> /div> !-- Google Tag Manager -->noscript>iframe src//www.googletagmanager.com/ns.html?idGTM-MSPWGQ height0 width0 styledisplay:none;visibility:hidden>/iframe>/noscript>script>(function(w,d,s,l,i){wlwl||;wl.push({gtm.start: new Date().getTime(),event:gtm.js});var fd.getElementsByTagName(s)0, jd.createElement(s),dll!dataLayer?&l+l:;j.asynctrue;j.src //www.googletagmanager.com/gtm.js?id+i+dl;f.parentNode.insertBefore(j,f); })(window,document,script,dataLayer,GTM-MSPWGQ);/script>!-- End Google Tag Manager -->script> dataLayer.push({is_ad_display:true})/script> div classexHeader exHeader_0 idexHeader> div idexlogo> a hrefhttps://www.exblog.jp/ titleエキサイトブログ idexlogoblog>/a> /div> div idexHeader_ranking> a hrefhttps://www.exblog.jp/ranking/>人気ブログランキング/a> | a hrefhttps://www.exblog.jp/tag/>話題のタグを見る/a> /div> div idexSearch> form methodget namesearch actionhttps://www.exblog.jp/search/> label forsearch_text>/label>input typetext nameq idsearch_text size18 value> label> select namet classsearch_select> option value1 selectedselected>投稿内容/option> option value2>タグ/option> option value4>ブログタイトル/option> option value3>ウェブ全体/option> /select> /label> input typesubmit value idsearch_submit> /form> /div> ul idtoollink> li>a hrefhttps://ssl2.excite.co.jp/idc/login/?siblog&ruhttps%3A%2F%2Fblog.excite.co.jp%2Fauth%2F%3Fru%3Dhttps%3A%2F%2Fkonishilab.exblog.jp%2F relnofollow>ログイン/a>|/li> li>a hrefhttps://www.exblog.jp/new/pr/>ブログ開設・作成（無料）/a>/li> /ul> /div> div idgpt_pc_blog_billboard> script defer src//image.excite.co.jp/jp/ox/gpt/display/pc/blog/pc_blog_billboard.js>/script> /div> div idbase>div idheader> div idheader_text> p>a hrefhttps://konishilab.exblog.jp/>konishilab.exblog.jp/a>/p> h1>a hrefhttps://konishilab.exblog.jp/>東京科学大学（東京工業大学）物質理工学院応用化学系・小西研 論文リスト (List of Publications, Dr. Gen-ichi KONISHI)/a>/h1> p classadminmenu>a hrefhttps://www.exblog.jp/>ブログトップ/a>/p> /div> img srchttp://md.exblog.jp/skn/img/a/01/09/3/folder.gif classclover titleclover_folder width64 height43 altトランスメディアGP />/div>div idcontents> div classpost> div classpost_title> h2> a hrefhttps://konishilab.exblog.jp/35261779/>2025-10/a> /h2> /div> p> /p> div classstory> !-- interest_match_relevant_zone_start --> b stylefont-size: medium;>span stylecolor: rgb(255, 0, 0);>Open Access/span>/b>br>div>font style>b stylefont-size: medium;>Chemotherapy resistance due to epithelial-to-mesenchymal transition is caused by abnormal lipid metabolic balance/b>br>span stylefont-size: medium;>A. Matsumoto, A. Inoko, T. Tanaka, G. Konishi, W. Hosoda, T. Kojima, K. Ohnishi, J. Ikenouchi/span>br>b stylefont-size: medium;>a hrefhttps://elifesciences.org/ target_blank>eLife /a>/b>span stylefont-size:medium;> b style>13/b>, preprint (2025)/span>br>span stylefont-size: medium;>DOI: 10.1101/2024.10.22.619604/span>br>b stylefont-size: medium;>a hrefhttps://www.biorxiv.org/content/10.1101/2024.10.22.619604v2.abstract target_blank>Link/a>/b>br>font style>span stylefont-size: medium;>Abstract: Invasive cancer is defined by the loss of epithelial cell traits resulting from the ectopic expression of epithelial-mesenchymal transition (EMT)-related transcription factors such as Snail. Although EMT is known to impart chemoresistance to cancer cells, the precise molecular mechanisms remain elusive. We found that Snail expression confers chemoresistance by upregulating the cholesterol efflux pump ABCA1 as a countermeasure to the excess of cytotoxic free cholesterol relative to its major interaction partner in cellular membranes, sphingomyelin. This imbalance is introduced by the transcriptional repression of enzymes involved in the biosynthesis of sphingomyelin by Snail. Inhibiting esterification of cholesterol, which renders it inert, selectively suppresses growth of a xenograft model of Snail-positive kidney cancer. Our findings offer a new perspective on lipid-targeting strategies for invasive cancer therapy. /span>/font>br>/font>/div> br classclear/> !-- interest_match_relevant_zone_end --> div classsm_icon_mini> /div> div classbbs_preview> /div> /div> p classposttail> a hrefhttps://konishilab.exblog.jp/35261779/>#/a> span classTIME> by span classAUTHOR>konishi_lab/span> | a hrefhttps://konishilab.exblog.jp/35261779/>2025-11-01 09:52/a> | a hrefhttps://konishilab.exblog.jp/i23/>2025 (11)/a> /span>div idhx-comment-target-35261779>/div> /p> span idcmt35261779 data-ex-idform-35261779>/span> div classstory_footer>/div>/div>div classpost> div classpost_title> h2> a hrefhttps://konishilab.exblog.jp/35161684/>1000 Citations!!/a> /h2> /div> p> /p> div classstory> !-- interest_match_relevant_zone_start --> b stylefont-size: medium;>span stylecolor: rgb(255, 0, 0);>News/span>/b>br>div>font style>b stylefont-size: medium;>The review article on TICT published in J. Mater. Chem. C in 2016 DOI: 10.1039/c5tc03933a has reached 1,000 citations./b>br>/font>/div>center>img srchttps://pds.exblog.jp/pds/1/202510/19/36/b0202136_20491846.jpg alt1000 Citations!!_b0202136_20491846.jpg classIMAGE_MID height210 width500 stylecursor: pointer; data-ex-idopen-image-dialog data-ex-value202510/19/36/b0202136_20491846.jpg />/center> br classclear/> !-- interest_match_relevant_zone_end --> div classsm_icon_mini> /div> div classbbs_preview> /div> /div> p classposttail> a hrefhttps://konishilab.exblog.jp/35161684/>#/a> span classTIME> by span classAUTHOR>konishi_lab/span> | a hrefhttps://konishilab.exblog.jp/35161684/>2025-10-19 20:56/a> | a hrefhttps://konishilab.exblog.jp/i8/>News/a> /span>div idhx-comment-target-35161684>/div> /p> span idcmt35161684 data-ex-idform-35161684>/span> div classstory_footer>/div>/div>div classpost> div classpost_title> h2> a hrefhttps://konishilab.exblog.jp/34642516/>2025-9/a> /h2> /div> p> /p> div classstory> !-- interest_match_relevant_zone_start --> b stylefont-size: medium;>span stylecolor: rgb(255, 0, 0);>Open Access/span>/b>br>div>font style>b stylefont-size: medium;>Rod-like liquid crystalline molecules with ring-fixed benzanilides/b>br>span stylefont-size: medium;>Y. Sawatari, T. Kajitani, E. Tsurumaki, G. Konishi*/span>br>b stylefont-size: medium;>a hrefhttps://www.tandfonline.com/journals/tlct20 target_blank>Liq. Cryst. /a>/b>span stylefont-size:medium;> b style>52/b>, xxx (2025)/span>br>span stylefont-size: medium;>DOI: 10.1080/02678292.2025.2542876/span>br>b stylefont-size: medium;>a hrefhttps://doi.org/10.1080/02678292.2025.2542876 target_blank>Link/a>/b>br>font style>span stylefont-size: medium;>Abstract: Rod-like liquid crystals (LCs) consist of a linear rigid core and flexible hydrocarbon chains, and the resulting LC properties are significantly affected by these chemical structures. In designing rod-like LCs, tertiary amides are rarely employed, owing to their stability in the cis conformation (bent shape), while secondary amides have been utilised because of their stability in the trans conformation (rod-like shape). In this study, we synthesised rod-like LCs incorporating ring-fixed benzanilides, in which the Ar-CO and amide bonds are fixed, denoted asb> PBAn/b> (n 5, 6, 7). Their properties were evaluated through polarised optical microscopy, differential scanning calorimetry, and wide-angle X-ray diffraction measurements. The findings indicate that the LC properties can be modulated by varying the ring size. Furthermore, single-crystal structural analysis revealed the molecular alignment potential enabled facilitated by the ring-fixed benzanilide. /span>/font>br>/font>/div>center>img srchttps://pds.exblog.jp/pds/1/202507/10/36/b0202136_15405793.jpg alt2025-9_b0202136_15405793.jpg classIMAGE_MID height240 width500 stylecursor: pointer; data-ex-idopen-image-dialog data-ex-value202507/10/36/b0202136_15405793.jpg />/center> br classclear/> !-- interest_match_relevant_zone_end --> div classsm_icon_mini> /div> div classbbs_preview> /div> /div> p classposttail> a hrefhttps://konishilab.exblog.jp/34642516/>#/a> span classTIME> by span classAUTHOR>konishi_lab/span> | a hrefhttps://konishilab.exblog.jp/34642516/>2025-08-11 22:38/a> | a hrefhttps://konishilab.exblog.jp/i23/>2025 (11)/a> /span>div idhx-comment-target-34642516>/div> /p> span idcmt34642516 data-ex-idform-34642516>/span> div classstory_footer>/div>/div>div classpost> div classpost_title> h2> a hrefhttps://konishilab.exblog.jp/34590438/>2025-8/a> /h2> /div> p> /p> div classstory> !-- interest_match_relevant_zone_start --> font style>b stylefont-size: medium;>Viscosity Responsiveness of Excited-State Dynamics in Aggregated-Induced Emission Luminogens/b>br>span stylefont-size: medium;>T. Tanaka, R. Noda, Y. Sawatari, R. Iwai, B. Z. Tang, G. Konishi*/span>br>b stylefont-size: medium;>a hrefhttps://www.sciencedirect.com/journal/chinese-chemical-letters target_blank>Chin. Chem. J./a>/b>span stylefont-size:medium;> b style>36/b>, 111495 (2025)/span>br>span stylefont-size: medium;>DOI: 10.1016/j.cclet.2025.111495/span>br>b stylefont-size: medium;>a hrefhttps://doi.org/10.1016/j.cclet.2025.111495 target_blank>Link/a>/b>br>span stylecolor: rgb(255, 102, 198);>b style>span stylefont-size: medium;>span stylefont-size: medium;>span stylefont-size: medium;>Chinese Chemical Leters: impact factor 2024 8.9/span>/span>/span>/b>/span>br>font size3>b>a hrefhttps://www.isct.ac.jp/ja/news/udph8v17bpw1 target_blank>span stylecolor:#0090ff>東京科学大 研究成果2025年8月6日（日本語）/span>/a>/b>br>b>a hrefhttps://www.isct.ac.jp/plugins/cms/component_download_file.php?type2&pageId&contentsId1&contentsDataId2085&prevId&key7e8893adbabcdb8bb577950988301a1f.pdf&fileNamesciencetokyopr20250804-konishi target_blank>span stylecolor: rgb(255, 0, 0);>span stylecolor:#0090ff>プレスリリース PDF/span>/span>/a>/b>/font>br>/font>center>img srchttps://pds.exblog.jp/pds/1/202503/25/36/b0202136_07320876.jpg alt2025-8_b0202136_07320876.jpg classIMAGE_MID height419 width500 stylecursor: pointer; data-ex-idopen-image-dialog data-ex-value202503/25/36/b0202136_07320876.jpg />/center>font style>span stylefont-size: medium;>Abstract: Aggregation-induced emission luminogens (AIEgens) exhibit viscosity-responsive behavior resembling those of molecular rotors; however, their response mechanisms are more complex and cannot be adequately described using simple rotational models. AIEgens demonstrate intricate dynamics that are highly dependent on their molecular structures. In this study, we synthesized water-soluble derivatives of representative AIEgens, including tetraphenylethene (TPE), bis(N,N-dialkylamino)anthracene (BDAA), and bridged stilbene, and systematically investigated the dependence of their photophysical properties in water/glycerol mixed solvents on temperature and viscosity. To elucidate the origin of their viscosity responsiveness, quantum chemical calculations were conducted to analyze their potential energy surfaces (PES). The results revealed that compared to typical molecular rotors, these AIEgens exhibit significantly higher sensitivity to viscosity in low-viscosity regions. Notably, for TPE and BDAA derivatives, the viscosity responsiveness was found to be governed not by the activation energy barrier (ΔEa) based on the PES, but rather by the viscosity-dependent constraints on molecular structural changes. Furthermore, molecules possessing multiple aromatic rings or large, flexible, rotatable moieties were found to exhibit enhanced sensitivity to viscosity due to increased frictional interactions in solutions. This study provides critical insights into the mechanistic origins of the viscosity responsiveness of AIEgens, thereby advancing the fundamental understanding of their behavior and expanding their potential application as viscosity-sensitive probes. /span>/font>br> br classclear/> !-- interest_match_relevant_zone_end --> div classsm_icon_mini> /div> div classbbs_preview> /div> /div> p classposttail> a hrefhttps://konishilab.exblog.jp/34590438/>#/a> span classTIME> by span classAUTHOR>konishi_lab/span> | a hrefhttps://konishilab.exblog.jp/34590438/>2025-08-09 16:00/a> | a hrefhttps://konishilab.exblog.jp/i23/>2025 (11)/a> /span>div idhx-comment-target-34590438>/div> /p> span idcmt34590438 data-ex-idform-34590438>/span> div classstory_footer>/div>/div>div classpost> div classpost_title> h2> a hrefhttps://konishilab.exblog.jp/34589786/>2025-7/a> /h2> /div> p> /p> div classstory> !-- interest_match_relevant_zone_start --> b stylefont-size: medium;>span stylecolor: rgb(255, 0, 0);>Open Access, Invited Paper/span>/b>br>font style>b stylefont-size: medium;>Development of 2,1,3-benzothiadiazole-based Room-temperature Fluorescent Nematic Liquid Crystals/b>br>span stylefont-size: medium;>M. S. Uzair, Y. Shimomura, T. Tanaka, G. Konishi* /span>br>b stylefont-size: medium;>a hrefhttps://www.mdpi.com/journal/molecules target_blank>Molecules /a>/b>span stylefont-size:medium;> b style>30/b>, 2438 (2025)/span>br>span stylefont-size: medium;>DOI: 10.3390/molecules30112438/span>br>b stylefont-size: medium;>a hrefhttps://doi.org/10.3390/molecules30112438 target_blank>Link/a>/b>br>center>img srchttps://pds.exblog.jp/pds/1/202505/30/36/b0202136_17565121.jpg alt2025-7_b0202136_17565121.jpg classIMAGE_MID height243 width500 stylecursor: pointer; data-ex-idopen-image-dialog data-ex-value202505/30/36/b0202136_17565121.jpg />/center>font style>span stylefont-size: medium;>Abstract: Fluorescent liquid crystals (LCs) have attracted considerable interest owing to their unique combination of fluidity, anisotropy, and intrinsic emission. However, most reported fluo-rescent LCs exhibit high phase transition temperatures and/or smectic phases, limiting their practical applications. To address this, we designed and synthesized a series of 2,1,3-benzothiadiazole (BTD)-based fluorescent nematic liquid crystals incorporating do-nor (D) or acceptor (A) groups to form D–A–D or D–A–A structures. Most of the synthe-sized derivatives exhibited supercooled nematic phases at room temperature. They com-posed various functional groups, such as secondary alkylamine, branched alkyl chain, and trifluoroacetyl groups, which are rarely used in calamitic nematic LCs. Notably, di-methylamine- and carbonyl-substituted derivatives exhibited relatively high fluorescence quantum yields (Φfl) in both solid and mesophase states, demonstrating their potential as efficient fluorescent materials. Our findings underscore the versatility of BTD-based mesogenic skeletons for designing room-temperature fluorescent nematic LCs with vari-ous functional groups. These materials offer promising opportunities for next-generation display technologies, optical sensors, and photonic applications./span>/font>br>/font> br classclear/> !-- interest_match_relevant_zone_end --> div classsm_icon_mini> /div> div classbbs_preview> /div> /div> p classposttail> a hrefhttps://konishilab.exblog.jp/34589786/>#/a> span classTIME> by span classAUTHOR>konishi_lab/span> | a hrefhttps://konishilab.exblog.jp/34589786/>2025-06-20 11:27/a> | a hrefhttps://konishilab.exblog.jp/i23/>2025 (11)/a> /span>div idhx-comment-target-34589786>/div> /p> span idcmt34589786 data-ex-idform-34589786>/span> div classstory_footer>/div>/div> div classpagerNavLink>span classcurrent>1/span>a hrefhttps://konishilab.exblog.jp/page/2/>2/a>a hrefhttps://konishilab.exblog.jp/page/3/>3/a>a hrefhttps://konishilab.exblog.jp/page/4/>4/a>a hrefhttps://konishilab.exblog.jp/page/5/>5/a>span classnextpage>a hrefhttps://konishilab.exblog.jp/page/2/>次へ >/a>/span>span classlast>a hrefhttps://konishilab.exblog.jp/page/34/>>>/a>/span>/div> p classpageGuide> /p>/div>div idnavigation> div classprofile> img srchttps://pds.exblog.jp/logo/1/201008/20/36/b020213620130202002817.jpg classLOGO width170 height218 border0 stylecursor: pointer; 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